Issue 15, 1992

Preferential formation of amino acid esters in aqueous alcohol solutions: solvolysis of 6,6′-bis(aminoacylamino)-2,2′-bipyridine by metal coordination

Abstract

Exclusive formation of amino acid esters took place at an appreciable rate in the CuII-catalysed solvolysis of 6,6′-(α-alanylamino or α-phenylalanylamino)-2,2′-bipyridine in alcohol–borate buffer (pH 7.2) solutions at 20 °C via formation of an amide-O-coordinated complex, even though appreciable amounts of water (0–40% v/v) were present in the solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1060-1062

Preferential formation of amino acid esters in aqueous alcohol solutions: solvolysis of 6,6′-bis(aminoacylamino)-2,2′-bipyridine by metal coordination

K. Araki, T. Kuboki, M. Yamada and S. Shiraishi, J. Chem. Soc., Chem. Commun., 1992, 1060 DOI: 10.1039/C39920001060

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