Reaction of HgBr2 with sodium cyclohexanethiolate in methanol, followed by recrystallisation from pyridine, gives the discrete molecular complex [Hg7(SC6H11)12Br2], in which six Hg atoms form a distroted octahedron around a central Br, thiolate ligands are bridging or terminal, and a HgBr unit with terminal Br caps three thiolates on one side of the molecule.
T. Alsina, W. Clegg, K. A. Fraser and J. Sola, J. Chem. Soc., Chem. Commun., 1992, 1010 DOI: 10.1039/C39920001010
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