High levels of regio-, stereo- and enantio-selectivity are achieved in the asymmetric synthesis of six-membered oxygen heterocycles via intramolecular C–H insertion reactions of α-diazoketones catalysed by chiral rhodium(II) carboxylates.
M. A. McKervey and T. Ye, J. Chem. Soc., Chem. Commun., 1992, 823 DOI: 10.1039/C39920000823
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