Issue 10, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Ligand C–C bond cleavage on ruthenium: observation of a reversible ruthenium(V)–imido/ruthenium(II)–amine couple and X-ray crystal structure of [Ru(bpy)2(NH[double bond, length half m-dash]CMe2)2](PF6)2(bpy = 2,2′-bipyridine)

Kwok-Yin Wong,   Chi-Ming Che,   Chi-Keung Li,   Wing-Hong Chiu,   Zhong-Yuan Zhou  and  Thomas C. W. Mak  

Abstract

A reversible three-proton three-electron couple has been observed for the electrochemical oxidation of cis-[Ru(bpy)2(L)]2+(L = 2,3-dimethyl-2,3-diaminobutane) in aqueous acidic solution; controlled-potential electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ led to C–C bond cleavage in L and formation of cis-[Ru(bpy)2(NH[double bond, length half m-dash]CMe2)2]2+ whose structure has been determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39920000754
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 754-756

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Ligand C–C bond cleavage on ruthenium: observation of a reversible ruthenium(V)–imido/ruthenium(II)–amine couple and X-ray crystal structure of [Ru(bpy)2(NH[double bond, length half m-dash]CMe2)2](PF6)2(bpy = 2,2′-bipyridine)

K. Wong, C. Che, C. Li, W. Chiu, Z. Zhou and T. C. W. Mak, J. Chem. Soc., Chem. Commun., 1992, 754 DOI: 10.1039/C39920000754

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