Issue 9, 1992

Investigation of [IrH2(Me2CO)2(PPh3)2]BF4 as a catalyst of hydrogen isotope exchange of substrates in solution

Abstract

The title complex is found to catalyse the efficient and regioselective exchange of deuterium gas with hydrogens in several substrate structural types; exchange is observed only at aromatic sites in proximity to certain nitrogen or oxygen containing functional groups, but not all such sites undergo exchange.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 680-681

Investigation of [IrH2(Me2CO)2(PPh3)2]BF4 as a catalyst of hydrogen isotope exchange of substrates in solution

R. Heys, J. Chem. Soc., Chem. Commun., 1992, 680 DOI: 10.1039/C39920000680

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