Rh-complex catalysed directed hydrogenation of (α-hydroxyalkyl)vinyl sulfones follows the same stereochemical course as the corresponding acrylates, via HO-coordination; hydrogenation of the related (α-hydroxyalkyl)vinyl sulfoxides is directed by S–O coordination, which overrides HO-participation and is shown to be general.
D. Ando, C. Bevan, J. M. Brown and D. W. Price, J. Chem. Soc., Chem. Commun., 1992, 592 DOI: 10.1039/C39920000592
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