Issue 6, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and reactivity of dinuclear µ-silyl complexes of ruthenium having three-centre two-electron Ru–H–Si interactions

Hiroharu Suzuki,   Toshiro Takao,   Masako Tanaka  and  Yoshihiko Moro-oka  

Abstract

Reaction of [(C5Me5)Ru(µ-H)4Ru(C5Me5)] with R2SiH2 yields the dinuclear µ-silyl complexes [{(C5Me5)Ru(µ-η2-HSiR2)}2(µ-H)(H)]2a, R = Et; 2b, R = Ph, having three-centre two-electron interactions, and pyrolysis of 2b in refluxing toluene affords a dinuclear µ-silylene (silanediyl) complex [(C5Me5)Ru(µ-SiPh2)2(µ-H)2Ru(C5Me5)]3; the molecular structures of 2a and 3 have been determined by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39920000476
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 476-478

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Synthesis and reactivity of dinuclear µ-silyl complexes of ruthenium having three-centre two-electron Ru–H–Si interactions

H. Suzuki, T. Takao, M. Tanaka and Y. Moro-oka, J. Chem. Soc., Chem. Commun., 1992, 476 DOI: 10.1039/C39920000476

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