SCHEDULED MAINTENANCE:
Photoxygenation of digermirane 1a and azadigermiridine 1b using tetraphenylporphine as sensitizer affords the corresponding peroxides, 1,2,3,5-dioxazadigermolane 2a and 1,2,4,3,5-dioxazadigermoridine 2b, respectively in good yields; 2a is structurally characterized by X-ray analysis.
M. Kako, T. Akasaka and W. Ando, J. Chem. Soc., Chem. Commun., 1992, 457 DOI: 10.1039/C39920000457
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