3,5,9,11-Tetraoxotridecanedioates containing C-glycoside units on the side chain were generated from 1-hydroxy sugars, β-ketoglutarate and acetoacetate; intramolecular condensation of the polyketide compounds gave C-glycosidic naphthalene-1,8-diols regio- and stereo-selectively.
M. Yamaguchi, A. Horiguchi, C. Ikeura and T. Minami, J. Chem. Soc., Chem. Commun., 1992, 434 DOI: 10.1039/C39920000434
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