A low yield of 4-methylpent-2-yne in the gas-phase isomerisation of 1,3,3-trimethylcyclopropene is shown to be more consistent with an alkylidene carbene transient than with a, 1,3-biradical intermediate.
R. Walsh, C. Wolf, S. Untiedt and A. de Meijere, J. Chem. Soc., Chem. Commun., 1992, 421 DOI: 10.1039/C39920000421
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