A model system for mimicry of the protochlorophyllide reductase enzymatic process, consisting of a zinc porphyrin covalently linked to a dihydroflavin, undergoes two successive one-electron transfer steps upon illumination, forming a zinc porphodimethene and the corresponding flavin.
P. Nayar, A. M. Brun, A. Harriman and T. P. Begley, J. Chem. Soc., Chem. Commun., 1992, 395 DOI: 10.1039/C39920000395
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