Issue 4, 1992

Intermolecular magnetic interactions in a mixed-valence compound: inelastic neutron scattering spectrum of [FeIII2FeIIO(O2CCD3)6(C5D5N)3](C5D5N)

Abstract

An inelastic neutron scattering spectrum of the mixed-valence compound [FeIII2FeIIO(O2CCD3)6(C5D5N)3](C5D5N) shows 11 energy transfers in the frequency range 2–25 cm–1, which disappear on dilution in a host lattice, indicating intermolecular origin; this is the first evidence of strong intermolecular electronic interactions in a mixed-valence system.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 379-381

Intermolecular magnetic interactions in a mixed-valence compound: inelastic neutron scattering spectrum of [FeIII2FeIIO(O2CCD3)6(C5D5N)3](C5D5N)

U. A. Jayasooriya, R. D. Cannon, C. E. Anson, S. K. arapKoske, R. P. White and G. J. Kearley, J. Chem. Soc., Chem. Commun., 1992, 379 DOI: 10.1039/C39920000379

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