Issue 4, 1992

trans-[Na(thf)][V(N2)2(Ph2PCH2CH2PPh2)2]: structural characterization of a dinitrogenvanadium complex, a functional model for vanadiumnitrogenase

Abstract

Reduction of VCl3(thf)3(thf = tetrahydrofuran) by Na in the presence of bis(phosphines) and N2 yields the complexes trans-[V(N2)2L2], which have been structurally characterized by X-ray crystallography for L = Ph2PCH2CH2PPh2, and in solution by 51V NMR spectroscopy for L = Me2PCH2CH2PMe2; 25% of the coordinated N2 is reductively protonated to NH3 and a small amount of N2H4 by HBr.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 364-365

trans-[Na(thf)][V(N2)2(Ph2PCH2CH2PPh2)2]: structural characterization of a dinitrogenvanadium complex, a functional model for vanadiumnitrogenase

D. Rehder, C. Woitha, W. Priebsch and H. Gailus, J. Chem. Soc., Chem. Commun., 1992, 364 DOI: 10.1039/C39920000364

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