Synthesis and crystal and molecular structure of (NH4)4[V10O16{EtC(CH2O)3}4]·4H2O, a decavanadyl cluster
Abstract
The hydrothermal reaction of (NH4)VO3 with EtC(CH2OH)3 yields the oxoalkoxovanadium(IV) cluster, (NH4)4[V10O16{EtC(CH2O)3}4]·4H2O, an unusual polyoxoanion coordination complex with a reduced {V10O28} core.