The synthesis and X-ray crystal structure of the dimeric five-coordinate homoleptic thorium alkoxide [Th(OCHPri2)4]2, the first X-ray structural characterisation of a homoleptic thorium alkoxide complex, are reported: 1H NMR findings evidence an equilibrium between the dimer [Th(OCHPri2)4]2 and its monomer [Th(OCHPri2)4].
D. L. Clark, J. C. Huffman and J. G. Watkin, J. Chem. Soc., Chem. Commun., 1992, 266 DOI: 10.1039/C39920000266
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