The chiral-at-metal niobium nitrene compounds [Nb(η-C5H5)(N-2,6-Pri2C6H3)(PMe3)(L)](L = CO, C2H4, C3H6and RC![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CR) have been prepared via the dichloride [Nb(η-C5H5)(N-2,6-Pri2C6H3)Cl2] and the molecular structure of the propene derivative has been determined.
A. D. Poole, V. C. Gibson and W. Clegg, J. Chem. Soc., Chem. Commun., 1992, 237 DOI: 10.1039/C39920000237
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