Protonation of an {MnIV(µ2-O)}2 core to form {(MNIV)2(µ2-O)(µ2-OH)} leads to perturbations of the physical properties of this unit including an increase in metal–metal separation (ca. 0.1 Å) and loss of catalase reactivity.
E. J. Larson, P. J. Riggs, J. E. Penner-Hahn and V. L. Pecoraro, J. Chem. Soc., Chem. Commun., 1992, 102 DOI: 10.1039/C39920000102
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