A cyclic trimeric porphyrin host is synthesised from monomer via alkyne–platinum–alkyne linkages; binding of the octahedral aluminum tris[3-(4-pyridyl)acetylacetonate] guest ligand into the complementary cavity of the host induces an asymmetry, which is readily detected by NMR spectroscopy.
L. G. Mackay, H. L. Anderson and J. K. M. Sanders, J. Chem. Soc., Chem. Commun., 1992, 43 DOI: 10.1039/C39920000043
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