Sterically distorted Fe–CN bonds created by ‘strapped’ iron(III) porphyrins exhibit a large upfield shift in the cyanide 15N NMR signal, making the steric effect on the distal side an important consideration in interpreting the 15N NMR spectra of cyanomet haemoproteins.
G. Avilés and C. K. Chang, J. Chem. Soc., Chem. Commun., 1992, 31 DOI: 10.1039/C39920000031
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