The efficient formation of a bicyclic oxazolidine by lithium aluminium hydride reduction of a tertiary amide provides an example of intramolecular nucleophilic capture of an iminium ion equivalent by the oxygen of a silyl ether.
N. G. Ramsden, G. W. J. Fleet and S. K. Namgoong, J. Chem. Soc., Perkin Trans. 2, 1991, 1991 DOI: 10.1039/P29910001991
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