Issue 11, 1991

Contributions of electrostatic and hydrophobic interactions to the host–guest complexation of pyrocatecholate anions with cationic cyclodextrins

Abstract

Binding constants of a series of 4-substituted pyrocatechols (1,2-dihydroxybenzenes) to four 6-deoxy, 6-amino derivatives of β-cyclodextrin have been determined from the kinetics of their auto-oxidation at pH 10.0. In several cases, the binding constants at pH 6.0 have been determined by spectrophotometry. Cationic forms of amino derivatives of β-cyclodextrin bind pyrocatecholate anions with equilibrium constants up to 105 dm3 mol–1. The electrostatic and hydrophobic interactions were shown to contribute additively to the free energy of the host–guest complexation.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1991, 1769-1772

Contributions of electrostatic and hydrophobic interactions to the host–guest complexation of pyrocatecholate anions with cationic cyclodextrins

A. K. Yatsimirsky and A. V. Eliseev, J. Chem. Soc., Perkin Trans. 2, 1991, 1769 DOI: 10.1039/P29910001769

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