SCHEDULED MAINTENANCE
Ferrocenylmethyl, dideuterio(ferrocenyl)methyl and 1′-methylferrocenylmethyl radicals have been prepared by γ-irradiation of the parent ferrocene derivatives in adamantane matrices. Ferrocenyl-methyl shows a triplet splitting (14.7 G) in its EPR spectrum attributed to the two α-protons; the couplings from the ring protons are buried in the linewidth. The high g value of 2.0200 indicates involvement of the Fe orbitals in the delocalized radical.
R. A. Jackson, M. Scarmoutsos and A. K. Zarkadis, J. Chem. Soc., Perkin Trans. 2, 1991, 809 DOI: 10.1039/P29910000809
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