The ortho-regioselective synthesis of unsymmetrical hydroxylated biaryls is accomplished via metaltemplate arylation of different titanium and bromomagnesium phenolates with benzoquinone bis(dimethyl ketals). The results are interpreted in terms of the complex-induced proximity effect.
G. Sartori, R. Maggi, F. Bigi and G. Casnati, J. Chem. Soc., Perkin Trans. 1, 1991, 3059 DOI: 10.1039/P19910003059
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