Fructose 1,6-diphosphate aldolase has been used as a catalyst for the synthesis (1–15 mmol scales) of several unusual sugar derivatives, including 5-deoxy-D-fructose, 6-deoxy-6-chloro-D-fructose, 6-deoxy-6-vinyl-D-fructose, 5,7-dideoxy-7-azido-L-xylo-heptulose, 5-deoxy-L-xylo-heptulose, 5,7-dideoxy-7-amino-L-xylo-heptulose and 5-deoxy-5-acetamido-L-xylo-hexulose.
K. K.-C. Liu, R. L. Pederson and C. Wong, J. Chem. Soc., Perkin Trans. 1, 1991, 2669 DOI: 10.1039/P19910002669
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