A very efficient phase transfer reaction for the preparation of the homochiral substituted cyclopentenones 13, 15 and 17 from (R)-4-acetoxycyclopent-2-enone 1 in a chirality transfer process is reported. The synthetic applications of the reaction products are demonstrated.
H. Grebe, A. Lange, H. Riechers, K. Kieslich, W. Viergutz, P. Washausen and E. Winterfeldt, J. Chem. Soc., Perkin Trans. 1, 1991, 2651 DOI: 10.1039/P19910002651
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