Regiospecific syntheses of glycocitrine-II and acronycine have been achieved from 3-acetyl-4-chloro-2-cyanomethylquinoline which, in turn, has been prepared by two different routes, from the aniline and anthranilic acid derivatives methyl 3-anilino-2-cyano-3-(methylthio)prop-2-enoate and methyl N-(1-methyl-3-oxobut-1-enyl)anthranilate.
R. C. Anand and A. K. Sinha, J. Chem. Soc., Perkin Trans. 1, 1991, 2339 DOI: 10.1039/P19910002339
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