The silylmethyl groups of (dialkylaminomethyl)trimethylsilanes 1 undergo ready lithiation with butyllithium and the resulting mixtures when quenched with chlorotrimethylsilane or aldenydes afford N,N-dialkyl(2,2,4,4-tetramethyl-2,4-disilapentyl)amines 3 or (dialkylaminomethyl)(2-hydroxyalkyl)-dimethylsilanes 4.
K. Marumo, S. Inoue, Y. Sato and H. Kato, J. Chem. Soc., Perkin Trans. 1, 1991, 2275 DOI: 10.1039/P19910002275
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