Synthesis and Baeyer–Villiger oxidation of the series of bicyclic ketones 3 and 6 is described. The ratio of methine to methylene carbon migration in the oxidation was found to vary depending on the 5-endo and 7-anti substituents of the ketones. Possible reasons for the observed regioselectivity are discussed.
P. Hamley, A. B. Holmes, D. R. Marshall and J. W. M. MacKinnon, J. Chem. Soc., Perkin Trans. 1, 1991, 1793 DOI: 10.1039/P19910001793
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