The keto acetate 1 in fermenting yeast gives the diol 2 with high enantiomeric excess. The product arises from hydrolysis–reduction and is transformed into (+)-endo-brevicomin. The hydroxy acetate from direct reduction of 1 is racemic.
G. Pedrocchi-Fantoni and S. Servi, J. Chem. Soc., Perkin Trans. 1, 1991, 1764 DOI: 10.1039/P19910001764
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