Issue 7, 1991

Perkin communications. 4-(1,2,4-Triazolyl) cation: possible generation and reactions

Abstract

Thermolysis of N-(1,2,4-triazol-4-yl)-2,4,6-trimethylpyridinium tetrafluoroborate 3 in mesitylene–hexafluoroisopropyl solution gives a variety of products, but none derived from attack of the free nitrenium ion upon mesitylene; a possible explanation is a SET from trimethylpyridine to the nitrenium ion within the solvent cage.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1991, 1761-1762

Perkin communications. 4-(1,2,4-Triazolyl) cation: possible generation and reactions

R. A. Abramovitch, J. M. Beckert and W. T. Pennington, J. Chem. Soc., Perkin Trans. 1, 1991, 1761 DOI: 10.1039/P19910001761

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