Three linear α-ketoenamines were allowed to react with a series of cyclic and acyclic nitroolefins, to yield aminocyclopentene derivatives with high diastereoselectivity. The corresponding polysubstituted nitrocyclopentanones were obtained by hydrolysis, which also proceeded with a high degree of diastereoselectivity when the system was prochiral.
F. Felluga, P. Nitti, G. Pitacco and E. Valentin, J. Chem. Soc., Perkin Trans. 1, 1991, 1645 DOI: 10.1039/P19910001645
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