SCHEDULED MAINTENANCE
Acid-induced ring opening of adducts of furan and methoxydehydrobenzenes gives the naphthalenols derived from the more stable carbocation. The cycloadditions of methoxydehydrobenzenes containing a 3-methoxy group and 2-methoxyfuran are highly regiospecific. The adducts, being strained acetals, undergo ring opening to provide a convenient synthesis of naphthalenols.
R. G. F. Giles, A. B. Hughes and M. V. Sargent, J. Chem. Soc., Perkin Trans. 1, 1991, 1581 DOI: 10.1039/P19910001581
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