The prostanoids 31, 33 and 42 have been prepared from tri-O-acetyl-D-glucal 5. The key step in the formation of the prostaglandin analogues 31 and 33 involves the photocatalysed reaction between the thiocarbonate 4 and the allylstannane 21 leading to the stereocontrolled formation of a new carbon–carbon bond through a C-centred radical addition–elimination process.
M. J. Kelly and S. M. Roberts, J. Chem. Soc., Perkin Trans. 1, 1991, 787 DOI: 10.1039/P19910000787
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...