The unstable molecule fluoro(sulphido)boron, FB![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
S, has been detected by microwave spectroscopy in the gaseous products of the high-temperature reaction between F2S2 vapour and crystalline boron chips at 1100 °C. Accurate spectroscopic, geometric, quadrupole and dipole moment data have been derived: rI(F—B)= 1.284(3)Å, rs(BS)= 1.606(3)Å and µ= 1.086(5) D.
T. A. Cooper, S. Firth and H. W. Kroto, J. Chem. Soc., Faraday Trans., 1991, 87, 1499 DOI: 10.1039/FT9918701499
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