Issue 12, 1991

Investigation of the hydrolysis of [Sn(CH3)3(H2O)2]+ in aqueous solution by tin-119 nuclear magnetic resonance spectroscopy

Abstract

The hydrolysis of [Sn(CH3)3(H2O)2]+ has been investigated using 119Sn NMR spectroscopy in aqueous solution at 25°C and ionic strength 0.5 mol dm–3. The ionic strength was adjusted using KCl, KNO3 or NaClO4. The chemical-shift data were processed using the computer program EQNMR to yield the stability constants and the chemical shifts of the various species present in solution. The results are compared with literature data obtained using other techniques.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1991, 3427-3429

Investigation of the hydrolysis of [Sn(CH3)3(H2O)2]+ in aqueous solution by tin-119 nuclear magnetic resonance spectroscopy

M. J. Hynes, J. M. Keely and J. McManus, J. Chem. Soc., Dalton Trans., 1991, 3427 DOI: 10.1039/DT9910003427

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