Issue 22, 1991

Metal–metal interaction in polynuclear silver(I) complexes: spectroscopy, luminescent properties and X-ray crystal structure of [Ag3(dppp)2(MeCN)2(ClO4)2]+[dppp = bis(diphenylphosphinophenylphosphine)]

Abstract

The [Ag3(dppp)2(MeCN)2(ClO4)2]+ complex displays 1(dσ*→ pσ) transition at 288 nm and solid state photoluminescence at 467 nm; the Ag–Ag distances are 2.943–-3. 014 (2)Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1615-1617

Metal–metal interaction in polynuclear silver(I) complexes: spectroscopy, luminescent properties and X-ray crystal structure of [Ag3(dppp)2(MeCN)2(ClO4)2]+[dppp = bis(diphenylphosphinophenylphosphine)]

C. Che, H. Yip, D. Li, S. Peng, G. Lee, Y. Wang and S. Liu, J. Chem. Soc., Chem. Commun., 1991, 1615 DOI: 10.1039/C39910001615

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