One-pot high-yield synthesis of the cubane-like complexes [{Mn(µ3-OH)(CO)3}4]1, and mixed-valence [Mn7(µ3-OH)8(CO)182, is reported: 1 and 2 have been characterized via X-ray crystallography, 2 being the largest Mn carbonyl complex yet structurally characterized.
M. D. Clerk and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1991, 1607 DOI: 10.1039/C39910001607
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