Issue 21, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of the 4,5-epoxybicyclo[7.3.0]dodecadiyne neocarzinostatin core structure. Surprising compatibility of the 4,5-epoxide with a η2-hexacarbonyldicobalt mediated aldol reaction

Philip Magnus  and  Martin Davies  

Abstract

The highly functionalized neocarzinostatin core structure 16 has been synthesized from the enynone 9 in a hexacarbonyldicobalt mediated aldol reaction in which the epoxide ring is unexpectedly not opened.

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Article information

DOI
https://doi.org/10.1039/C39910001522
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1522-1524

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Synthesis of the 4,5-epoxybicyclo[7.3.0]dodecadiyne neocarzinostatin core structure. Surprising compatibility of the 4,5-epoxide with a η2-hexacarbonyldicobalt mediated aldol reaction

P. Magnus and M. Davies, J. Chem. Soc., Chem. Commun., 1991, 1522 DOI: 10.1039/C39910001522

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