The first unsubstituted neutral hypho carbaborane, C3B4H12, has been synthesised by hot–cold reaction of arachno-B4H10 with propyne; the compound is unusual in having three skeletal carbon atoms and a unique seven-vertex structure.
R. Greatrex, N. N. Greenwood and M. Kirk, J. Chem. Soc., Chem. Commun., 1991, 1510 DOI: 10.1039/C39910001510
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