Thermal rearrangement of the isocyanide alkyl complexes [Mo(η5-C5R5)(Me)(CO)2(CNBut)] 1, (R5= H5, 1a; H4Me, 1b; Me5, 1c) yields η2-iminoethyl-C,N complexes [Mo(η5-C5R5){η2-C(![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
NBut)Me3}(CO)2]2, and/or η3-aminoethylene-C,C′,N complexes [Mo(η5-C5R5){η3-H2CC(H)NBut}(CO)2]3, in reactions whose course is dramatically solvent dependent.
E. Carmona, P. J. Daff, A. Monge, P. Palma, M. L. Poveda and C. Ruiz, J. Chem. Soc., Chem. Commun., 1991, 1503 DOI: 10.1039/C39910001503
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