Issue 21, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Rearrangement of the phosphonium methyl iron complex [FeCp(CO)2CH2(PEt2H)]+ BPh4– by β-hydrogen elimination (Cp = cyclopentadienyl)

Dennis M. Hester  and  Gilbert K. Yang  

Abstract

UV photolysis of the title compound yields FeCp(CO)2PEt2Me+ by β-elimination from the phosphonium methyl moiety with evidence for an intermediate η2-phosphmomethanide metal hydride complex.

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Article information

DOI
https://doi.org/10.1039/C39910001498
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1498-1499

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Rearrangement of the phosphonium methyl iron complex [FeCp(CO)2CH2(PEt2H)]+ BPh4– by β-hydrogen elimination (Cp = cyclopentadienyl)

D. M. Hester and G. K. Yang, J. Chem. Soc., Chem. Commun., 1991, 1498 DOI: 10.1039/C39910001498

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