SCHEDULED MAINTENANCE
The 17-electron cationic [Fp–acyl] intermediates generated by cerium ammonium nitrate (CAN) oxidation of Fp–acyl complexes in dry acetonitrile undergo a fast homolytic dissociation leading to alkyl radical species whose subsequent fate is dependent on the structural features and reaction conditions.
C. Amiens, G. Balavoine and F. Guibé, J. Chem. Soc., Chem. Commun., 1991, 1458 DOI: 10.1039/C39910001458
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