Issue 20, 1991

Solvent polarity controls oxidizing species in the photosensitized oxidation of N,N-dibenzylhydroxylamine

Abstract

A kinetic analysis of the 9,10-dicyanoanthracene-sensitized photooxidation of N,N-dibenzylhydroxylamine, giving α-phenyl-N-benzylnitrone and hydrogen peroxide in quantitative yields, reveals the participation of superoxide in acetonitrile and singlet oxygen in carbon tetrachloride as the major oxidizing species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1425-1427

Solvent polarity controls oxidizing species in the photosensitized oxidation of N,N-dibenzylhydroxylamine

T. Sakurai, Y. Uematsu, O. Tanaka and H. Inoue, J. Chem. Soc., Chem. Commun., 1991, 1425 DOI: 10.1039/C39910001425

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements