The direct conversion of an allylic alcohol to an α-alkylated carbonyl derivative may be achieved in a one-pot sequence via rhodium promoted isomerization of the derived lithium alkoxide or potassium triethylboronate complex.
G. L. Edwards, W. B. Motherwell, D. M. Powell and D. A. Sandham, J. Chem. Soc., Chem. Commun., 1991, 1399 DOI: 10.1039/C39910001399
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