Issue 19, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and reactivity of the formally unsaturated diruthenium diphosphazane-bridged species [Ru2(CO)4{µ-(RO)2PN(Et)P(OR)2}2](R = Me or Pri)

John S. Field,   Raymond J. Haines,   Jörg Sundermeyer  and  Stephen F. Woollam  

Abstract

Thermolysis of [Ru2(µ-CO)(CO)4{µ-(RO)2PN(Et)P(OR)2}2] or [Ru2H2(CO)4{µ-(RO)2PN(Et)P(OR)2}2](R = Me or Pri) under appropriate reaction conditions affords the formally unsaturated species [Ru2(CO)4{µ-(RO)2PN(Et)P(OR)2}2], which reacts spontaneously at room temperature with various substrates; the crystal structure of [Ru2(CO)4{µ-(PriO)2PN(Et)P(OPri)2}2] as well as that of [Ru2H2(CO)4{µ-(PriO)2PN(Et)P(OPri)2}2] is reported.

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Article information

DOI
https://doi.org/10.1039/C39910001382
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1382-1384

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Synthesis and reactivity of the formally unsaturated diruthenium diphosphazane-bridged species [Ru2(CO)4{µ-(RO)2PN(Et)P(OR)2}2](R = Me or Pri)

J. S. Field, R. J. Haines, J. Sundermeyer and S. F. Woollam, J. Chem. Soc., Chem. Commun., 1991, 1382 DOI: 10.1039/C39910001382

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