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Issue 19, 1991
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η-Arene complexes of scandium(0) and scandium(II)

Abstract

Cocondensation of scandium vapour with 1,3,5-tri-tert-butylbenzene affords the first example of a scandium(0) complex, the sandwich compound bis(η-1,3,5-tri-tert-butylbenzene)scandium; ESR and UV studies also the reveal the presence of a second compound from this reaction, formulated as a similarly unique example of scandium(II) arising from activation of one of the methyl groups of a tert-butyl ring substituent.

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Article type: Paper
DOI: 10.1039/C39910001372
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 1372-1373
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    η-Arene complexes of scandium(0) and scandium(II)

    F. G. N. Cloke, K. Khan and R. N. Perutz, J. Chem. Soc., Chem. Commun., 1991, 0, 1372
    DOI: 10.1039/C39910001372

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