Ionic–molecular isomerism in chlorophenylphosphoranes PhnPCl5 –n(1 ⩽n⩽ 3)
Abstract
Both ionic and molecular modifications of the three Chlorophenylphosphoranes PhnPCl5 –n(1 ⩽n⩽ 3) have been isolated for the first time as solids and all have been characterised by elemental analysis, Raman spectroscopy and 31P magic angle spinning (MAS) NMR spectroscopy.