Issue 17, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel reactivity of thiometallates: syntheses and structures of new transition metal sulphide clusters containing WRu2S6 and Ru2S2(SR)2 cores

Yasushi Mizobe,   Masayuki Hosomizu,   Jun-ichi Kawabata  and  Masanobu Hidai  

Abstract

Reaction of [(η5-C5Me5)RuCl2]2 with an excess of (NH4)2WS4 in THF at reflux gave [(µ2-S2){(η5-C5Me5)Ru}2(µ3-S)(µ2-S)2WS], whereas the analogous treatment of [(η5-C5Me5)RuCl(µ-SPri)2Ru(η5-C5Me5)Cl] with (NH4)2MS4(M = W, Mo) resulted in the formation of [(η5-C5Me5)Ru(µ-S2)(µ-SPri)2Ru(η5-C5Me5)].

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Article information

DOI
https://doi.org/10.1039/C39910001226
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1226-1227

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Novel reactivity of thiometallates: syntheses and structures of new transition metal sulphide clusters containing WRu2S6 and Ru2S2(SR)2 cores

Y. Mizobe, M. Hosomizu, J. Kawabata and M. Hidai, J. Chem. Soc., Chem. Commun., 1991, 1226 DOI: 10.1039/C39910001226

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