Photochemical reaction of naphthalene with 2-(diethylamino)ethanol shows a striking effect of solvent polarity on the reaction course, which is explained in terms of the intermediacy of a geminate radical ion pair in benzene and free radical ions in acetonitrile.
A. Ogawa, S. Oh, S. Satoh and Y. Shirota, J. Chem. Soc., Chem. Commun., 1991, 1195 DOI: 10.1039/C39910001195
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