Irradiation (60Co γ-rays) of the novel, cubic three-dimensional coordination polymer, tris(propynoato)scandium(III), induces a solid-state polymerization reaction; analysis of the structure indicates that the criterion of parallelism is not a necessary requirement for the reactivity of monoacetylenes in solids.
J. S. Brodkin and B. M. Foxman, J. Chem. Soc., Chem. Commun., 1991, 1073 DOI: 10.1039/C39910001073
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